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{{Short description|Ceramic material}}
{{redirect|TiN|the chemical element|Tin}}
{{chembox
| Verifiedfields = changed
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| ImageAlt = Brown powdered titanium nitride
| ImageSize = 280
| ImageFile2 =
| ImageAlt2 = The structure of sodium chloride; titanium nitride's structure is similar.
| IUPACName = Titanium nitride
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| UNII = 6RW464FEFF
| PubChem = 93091
| ChemSpiderID_Ref = {{chemspidercite|
| ChemSpiderID = 84040
| RTECS =
| EINECS = 247-117-5
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| Formula = TiN
| MolarMass = 61.874 g/mol
| Appearance =
| Odor = Odorless
| Solubility = insoluble
| SolubleOther =
| Density = 5.21 g/cm<sup>3</sup><ref name=crc>{{cite book |
| MeltingPtC = 2947
| MeltingPt_ref= <ref name=crc/>
| ThermalConductivity = 29 W/(m·K) (323
| MagSus = +38{{e|-6}} emu/mol
| BoilingPt =
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}}
| Section3 = {{Chembox Structure
| Structure_ref=<ref>{{cite journal |
| CrystalStruct = [[
| SpaceGroup = Fm<u style="text-decoration:overline">3</u>m, No. 225
| Coordination = Octahedral
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| Section4 = {{Chembox Thermochemistry
| Thermochemistry_ref =
| HeatCapacity = 24 J/(K·mol) (500 K)<ref name=th2>{{cite journal
| Entropy = −95.7 J/(K·mol)<ref name=th1>{{cite journal |
| DeltaHform = −336 kJ/mol<ref name=th1/>
| DeltaGfree =
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}}
}}
'''Titanium nitride''' ('''TiN'''; sometimes known as '''
Applied as a thin coating, TiN is used to harden and protect cutting and sliding surfaces, for decorative purposes (
==Characteristics==
TiN has a [[Vickers hardness]] of 1800–2100, hardness of {{val|31|4|u=GPa}},<ref name=":0" /> a [[modulus of elasticity]] of
TiN
TiN becomes [[superconductivity|superconducting]] at cryogenic temperatures, with critical temperature up to 6.0 K for single crystals.<ref>{{cite journal |last1=Spengler |first1=W. |display-authors=etal |year=1978 |title=Raman scattering, superconductivity, and phonon density of states of stoichiometric and nonstoichiometric TiN |journal=
==Natural occurrence==<!--Osbornite redirects here-->▼
[[Osbornite]] is a very rare natural form of titanium nitride, found almost exclusively in meteorites.<ref>{{cite web |title=Osbornite |publisher=Hudson Institute of Mineralogy |website=Mindat.org |url=http://www.mindat.org/min-3035.html |
==Uses==
A well-known use for TiN coating is for edge retention and corrosion resistance on machine tooling, such as [[drill bit]]s and [[milling cutter]]s, often improving their lifetime by a factor of three or more.<ref>{{cite web
▲A well-known use for TiN coating is for edge retention and corrosion resistance on machine tooling, such as [[drill bit]]s and [[milling cutter]]s, often improving their lifetime by a factor of three or more.<ref>{{cite web |url=http://www.tincoat.net/TiN.html|date=June 2014|title=Titanium Nitride (TiN) Coating|publisher=Surface Solutions Inc.
}}</ref>
Because of
Though less visible, [[thin film]]s of TiN are also used in [[microelectronics]], where they serve as a [[electrical conductivity|conductive]] connection between the active device and the metal contacts used to operate the circuit, while acting as a [[diffusion barrier]] to block the [[diffusion]] of the metal into the silicon. In this context, TiN is classified as a "barrier metal" (electrical resistivity ~ 25
Owing to their high biostability, TiN layers may also be used as electrodes in [[bioelectronics|bioelectronic applications]]
==Fabrication==
[[File:TiNCoatedPunches NanoShieldPVD Thailand.JPG|thumb|right|
The most common methods of TiN thin film creation are [[physical vapor deposition]] (PVD, usually [[sputter deposition]], [[cathodic arc deposition]] or [[Electron
Bulk ceramic objects can be fabricated by packing powdered metallic titanium into the desired shape, compressing it to the proper density, then igniting it in an atmosphere of pure nitrogen. The heat released by the chemical reaction between the metal and gas is sufficient to [[sintering|sinter]] the nitride reaction product into a hard, finished item. See [[powder metallurgy]].
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[[File:Smith&Wesson CKLPR.jpg|thumb|right|A knife with a titanium oxynitride coating]]
There are several commercially used variants of TiN that have been developed since 2010, such as titanium carbon nitride (TiCN), [[titanium aluminium nitride]] (TiAlN or AlTiN), and titanium aluminum carbon nitride, which may be used individually or in alternating layers with TiN. These coatings offer similar or superior enhancements in corrosion resistance and hardness, and additional colors ranging from light gray to nearly black, to a dark, [[Iridescence|iridescent]], bluish-purple, depending on the exact process of application. These coatings are becoming common on sporting goods, particularly [[knife|knives]] and [[handgun]]s, where they are used for both
==As a constituent in steel
Titanium nitride is also produced intentionally, within some steels, by judicious addition of titanium to the [[alloy]]. TiN forms at very high temperatures because of its very low [[Standard enthalpy change of formation|enthalpy of formation]], and even [[Nucleation|nucleates]] directly from the melt in secondary
▲Titanium nitride is also produced intentionally within some steels by judicious addition of titanium to the [[alloy]]. TiN forms at very high temperatures because of its very low [[Standard enthalpy change of formation|enthalpy of formation]], and even [[Nucleation|nucleates]] directly from the melt in secondary steelmaking. It forms discrete, micrometre-sized [[Cubic crystal system|cubic]] particles at [[Grain boundary|grain boundaries]] and triple points, and prevents [[grain growth]] by [[Ostwald ripening]] up to very high [[homologous temperature]]s. Titanium nitride has the lowest [[Solubility equilibrium|solubility product]] of any metal nitride or carbide in austenite, a useful attribute in [[microalloyed steel]] formulas.
▲==Natural occurrence==<!--Osbornite redirects here-->
▲[[Osbornite]] is a very rare natural form of titanium nitride, found almost exclusively in meteorites.<ref>{{cite web |website=Mindat.org |url=http://www.mindat.org/min-3035.html |title=Osbornite |publisher=Hudson Institute of Mineralogy |accessdate=Feb 29, 2016}}</ref><ref>{{cite web|url=http://webmineral.com/data/Osbornite.shtml#.V_cFauArJaQ|website=Mineralogy Database|title=Osbornite Mineral Data|date=Sep 5, 2012|accessdate=Oct 6, 2015|publisher=David Barthelmy}}</ref>
==References==
{{reflist|
{{Titanium compounds}}
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[[Category:Nitrides]]
[[Category:Titanium(III) compounds]]
[[Category:Semiconductor device fabrication]]
[[Category:Superhard materials]]
[[Category:Rock salt crystal structure]]
[[Category:Coatings]]
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