丁基锡酸：修订间差异
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Cat-a-lot：分类间移动：从Category:烃基金属到Category:烷基金属 |
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| NameEn = ''n''-Butyltin hydroxide oxide |
| NameEn = ''n''-Butyltin hydroxide oxide |
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|Section1={{Chembox Identifiers |
|Section1={{Chembox Identifiers |
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| CASNo = 2273-43-0 |
| CASNo = 2273-43-0 |
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| EINECS = 218-880-1 |
| EINECS = 218-880-1 |
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| Formula = C<sub>4</sub>H<sub>10</sub>O<sub>2</sub>Sn |
| Formula = C<sub>4</sub>H<sub>10</sub>O<sub>2</sub>Sn |
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| MolarMass = 208.83 |
| MolarMass = 208.83 |
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| Appearance = 白色吸湿性粉末<ref>Dunn, P.; Norris, T. Preparation of organotin compounds. ''Australia, Commonwealth, Dept. Supply, Defence Std. Lab., Rept.'', 1964. 269. CAN61: 18357.</ref> |
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| Appearance = 白色粉末<ref name=Alfa>[http://chemicals.thermofisher.cn/AlfaAesarApp/getpdf?contentId=ZH_CN_MSDS_87307 丁基锡酸 MSDS]. Alfa Aesar. [2017-7-28]</ref> |
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| Density = 1.46g·cm<sup>-3</sup><ref name=chem /> |
| Density = 1.46g·cm<sup>-3</sup><ref name=chem /> |
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|Section5={{Chembox Pharmacology |
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|Section6={{Chembox Explosive |
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|Section7={{Chembox Hazards |
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'''丁基锡酸'''是一种[[有机锡化合物]]，化学式为C<sub>4</sub>H<sub>9</sub>Sn(O)OH，可由C<sub>4</sub>H<sub>9</sub>SnX<sub>3</sub>在碱性条件下的水解得到。<ref>无机化学丛书. 第三卷 碳 硅 锗分族. 科学出版社. pp 448-449. 2.5.4 有机锡氧化物</ref>它和[[对甲苯磺酸]]反应生成{(BuSn)<sub>12</sub>(μ<sub>3</sub>-O)<sub>14</sub>(μ<sub>2</sub>-OH)<sub>6</sub>}<sup>2+</sup>[[原子簇|簇]]。<ref>Eychennebaron C, Ribot F, Nathalie Steunou A, et al. Reaction of Butyltin Hydroxide Oxide with p-Toluenesulfonic Acid: Synthesis, X-ray Crystal Analysis, and Multinuclear NMR Characterization of {(BuSn)<sub>12</sub>O<sub>14</sub>(OH)<sub>6</sub>(4-CH<sub>3</sub>C<sub>6</sub>H<sub>4</sub>SO<sub>3</sub>)<sub>2</sub>. ''Organometallics'', 2000, 19(10):1940-1949. DOI: 10.1021/om990877a</ref>丁基锡酸可用作[[催化剂]]。<ref name=chem>[http://www.chemicalbook.com/ProductChemicalPropertiesCB8428802.htm 丁基锡酸]. Chemical Book. [2017-7-28]</ref> |
'''丁基锡酸'''是一种[[有机锡化合物]]，化学式为C<sub>4</sub>H<sub>9</sub>Sn(O)OH，可由[[三氯化丁基锡|C<sub>4</sub>H<sub>9</sub>SnX<sub>3</sub>]]（X=[[卤素]]）在碱性条件下的水解得到。<ref>无机化学丛书. 第三卷 碳 硅 锗分族. 科学出版社. pp 448-449. 2.5.4 有机锡氧化物</ref>它和[[对甲苯磺酸]]反应生成{(BuSn)<sub>12</sub>(μ<sub>3</sub>-O)<sub>14</sub>(μ<sub>2</sub>-OH)<sub>6</sub>}<sup>2+</sup>[[原子簇|簇]]。<ref>Eychennebaron C, Ribot F, Nathalie Steunou A, et al. Reaction of Butyltin Hydroxide Oxide with p-Toluenesulfonic Acid: Synthesis, X-ray Crystal Analysis, and Multinuclear NMR Characterization of {(BuSn)<sub>12</sub>O<sub>14</sub>(OH)<sub>6</sub>(4-CH<sub>3</sub>C<sub>6</sub>H<sub>4</sub>SO<sub>3</sub>)<sub>2</sub>. ''Organometallics'', 2000, 19(10):1940-1949. DOI: 10.1021/om990877a</ref>丁基锡酸可用作[[催化剂]]。<ref name=chem>[http://www.chemicalbook.com/ProductChemicalPropertiesCB8428802.htm 丁基锡酸] {{Wayback|url=http://www.chemicalbook.com/ProductChemicalPropertiesCB8428802.htm |date=20171201023159 }}. Chemical Book. [2017-7-28]</ref> |
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==参考文献== |
==参考文献== |
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[[category:有机锡化合物]] |
[[category:有机锡化合物]] |
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[[Category:烷基金属]] |
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[[Category:正丁基化合物]] |
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2021年5月23日 (日) 08:41的最新版本
| 丁基锡酸 | |
|---|---|
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| 英文名 | n-Butyltin hydroxide oxide |
| 别名 | 正丁基锡酸 正丁基氢氧化氧化锡 |
| 识别 | |
| CAS号 | 2273-43-0 
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| EINECS | 218-880-1 |
| 性质 | |
| 化学式 | C4H10O2Sn |
| 摩尔质量 | 208.83 g·mol⁻¹ |
| 外观 | 白色吸湿性粉末[1] |
| 密度 | 1.46g·cm-3[2] |
| 危险性 | |
| 警示术语 | R：36/37/38 |
| 安全术语 | S：37/39-26 |
| 主要危害 | 有毒（T） |
| 若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。 | |
丁基锡酸是一种有机锡化合物，化学式为C4H9Sn(O)OH，可由C4H9SnX3（X=卤素）在碱性条件下的水解得到。[3]它和对甲苯磺酸反应生成{(BuSn)12(μ3-O)14(μ2-OH)6}2+簇。[4]丁基锡酸可用作催化剂。[2]
参考文献
[编辑]- ^ Dunn, P.; Norris, T. Preparation of organotin compounds. Australia, Commonwealth, Dept. Supply, Defence Std. Lab., Rept., 1964. 269. CAN61: 18357.
- ^ 2.0 2.1 丁基锡酸 （页面存档备份，存于互联网档案馆）. Chemical Book. [2017-7-28]
- ^ 无机化学丛书. 第三卷 碳 硅 锗分族. 科学出版社. pp 448-449. 2.5.4 有机锡氧化物
- ^ Eychennebaron C, Ribot F, Nathalie Steunou A, et al. Reaction of Butyltin Hydroxide Oxide with p-Toluenesulfonic Acid: Synthesis, X-ray Crystal Analysis, and Multinuclear NMR Characterization of {(BuSn)12O14(OH)6(4-CH3C6H4SO3)2. Organometallics, 2000, 19(10):1940-1949. DOI: 10.1021/om990877a
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